Nitrosyl Linkage Isomers: NO Coupling to N2O at a Mononuclear Site
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چکیده
منابع مشابه
Photoinduced linkage isomers of transition-metal nitrosyl compounds and related complexes.
The seminal discovery of light-induced changes in transition-metal nitrosyl complexes in the late 1970s and their identification as metastable linkage isomers almost 20 years after the initial discoveries have in recent years motivated a plethora of experimental and theoretical studies. They have raised the question of whether the linkage isomers play a role in the many crucial biological proce...
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The weak-field ligand environments at the metal nodes of metal-organic frameworks (MOFs) mimic the electronic environment of metalloenzyme active sites, but little is known about the reactivity of MOF nodes toward small molecules of biological relevance. Here, we report that the ferrous ions in Fe(2+)-exchanged MOF-5 disproportionate nitric oxide to produce nitrous oxide and a ferric nitrito co...
متن کاملCoordination and conformational isomers in mononuclear iron complexes with pertinence to the [FeFe] hydrogenase active site.
A series of six mononuclear iron complexes of the type [Fe(X-bdt)(P(R)2N(Ph)2)(CO)] (P(R)2N(Ph)2 = 1,5-diaza-3,7-diphosphaoctane, bdt = benzenedithiolate with X = H, Cl2 or Me and R = Ph, Bn, Cyc or tert-Bu) was prepared. This new class of penta-coordinate iron complexes contains a free coordination site and a pendant base as essential structural features of the [FeFe]-hydrogenase active site. ...
متن کاملComparing apples to oranges: just say no to N2O?
Submitted by admin on Mon, 09/08/2014 11:51am Title Comparing apples to oranges: just say no to N2O? Publication Type Journal Article Year of Publication 2013 Authors Vetter, TR, McGwin, G Journal Anesth Analg Volume 116 Issue 5 Pagination 959-61 Date Published 2013 May ISSN 1526-7598
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2019
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.8b09769